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Accessibility information
Author(s):   Anderson, W.F.; Bell, J.A.; Diamond, J.M.; Wilson, K.R.
Title:   Rate of thermal isomerization of cis-butene-2
Journal:   J. Am. Chem. Soc.
Volume:   80
Page(s):   2384 - 2386
Year:   1958
Reference type:   Journal article
Squib:   1958AND/BEL2384-2386

Reaction:   (Z)-2-C4H8(E)-2-C4H8
Reaction order:   1
Temperature:   664 - 716 K
Pressure:  0.27 - 0.53 bar
Rate expression:   1.0x1011 [s-1] e-217839 [J/mole]/RT
Bath gas:   (Z)-2-C4H8
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
664 7.31E-7
675 1.39E-6
700 5.56E-6
716 1.28E-5