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Title: Rate of thermal isomerization of cis-butene-2
Journal: J. Am. Chem. Soc.
Volume: 80
Page(s): 2384 - 2386
Year: 1958
Reference type: Journal article
Squib: 1958AND/BEL2384-2386
Reaction:
(Z)-2-C4H8 → (E)-2-C4H8
Reaction order:
1
Temperature:
664 - 716
K
Pressure: 0.27 - 0.53 bar
Rate expression:
1.0x1011 [s-1] e-217839 [J/mole]/RT
Bath gas:
(Z)-2-C4H8
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 664 | 7.31E-7 |
| 675 | 1.39E-6 |
| 700 | 5.56E-6 |
| 716 | 1.28E-5 |