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Author(s):   Rabinovitch, B.S.; Michel, K.W.
Title:   The thermal unimolecular cis-trans isomerization of cis-butene-2
Journal:   J. Am. Chem. Soc.
Volume:   81
Page(s):   5065 - 5071
Year:   1959
Reference type:   Journal article
Squib:   1959RAB/MIC5065-5071

Reaction:   (Z)-2-C4H8(E)-2-C4H8
Reaction order:   1
Temperature:   687 - 742 K
Pressure:  1.33E-5 - 0.99 bar
Rate expression:   6.1x1013 [s-1] e-262737 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
687 6.44E-7
700 1.51E-6
725 7.18E-6
742 1.95E-5