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Title: The thermal unimolecular cis-trans isomerization of cis-butene-2
Journal: J. Am. Chem. Soc.
Volume: 81
Page(s): 5065 - 5071
Year: 1959
Reference type: Journal article
Squib: 1959RAB/MIC5065-5071
Reaction:
(Z)-2-C4H8 → (E)-2-C4H8
Reaction order:
1
Temperature:
687 - 742
K
Pressure: 1.33E-5 - 0.99 bar
Rate expression:
6.1x1013 [s-1] e-262737 [J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 687 | 6.44E-7 |
| 700 | 1.51E-6 |
| 725 | 7.18E-6 |
| 742 | 1.95E-5 |