Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: Thermal isomerization of butene-2
Journal: Trans. Faraday Soc.
Volume: 57
Page(s): 1936 - 1941
Year: 1961
Reference type: Journal article
Squib: 1961CUN/PAL1936-1941
Reaction:
(Z)-2-C4H8 → (E)-2-C4H8
Reaction order:
1
Temperature:
683 - 749
K
Pressure: 1.33E-3 - 1.33E-2 bar
Rate expression:
1.78x1013 [s-1] e-252760 [J/mole]/RT
Bath gas:
(Z)-2-C4H8
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 683 | 8.32E-7 |
| 700 | 2.45E-6 |
| 725 | 1.10E-5 |
| 749 | 4.20E-5 |