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Title: Studies with a single-pulse shock tube. I. The cis-trans isomerization of butene-2
Journal: J. Chem. Phys.
Volume: 38
Page(s): 2056 - 2063
Year: 1963
Reference type: Journal article
Squib: 1963LIF/BAU2056-2063
Reaction:
(Z)-2-C4H8 → (E)-2-C4H8
Reaction order:
1
Temperature:
1000 - 1250
K
Pressure: 1.00E-1 - 0.29 bar
Rate expression:
3.5x1014 [s-1] e-271883 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1000 | 2.20E0 |
| 1025 | 4.89E0 |
| 1050 | 1.04E1 |
| 1075 | 2.15E1 |
| 1100 | 4.30E1 |
| 1125 | 8.33E1 |
| 1150 | 1.57E2 |
| 1175 | 2.87E2 |
| 1200 | 5.12E2 |
| 1225 | 8.93E2 |
| 1250 | 1.52E3 |