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Accessibility information
Author(s):   Jeffers, P.M.; Shaub, W.
Title:   Shock tube cis-trans isomerization studies
Journal:   J. Am. Chem. Soc.
Volume:   91
Page(s):   7706 - 7709
Year:   1969
Reference type:   Journal article
Squib:   1969JEF/SHA7706-7709

Reaction:   (Z)-2-C4H8(E)-2-C4H8
Reaction order:   1
Reference reaction:   tert-C4H9OHIsobutene + H2O
Temperature:   1040 - 1320 K
Pressure:  0.13 - 0.27 bar
Rate expression:   2.4x1013 [s-1] e-257749 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1040 2.72E0
1050 3.62E0
1075 7.18E0
1100 1.38E1
1125 2.59E1
1150 4.71E1
1175 8.36E1
1200 1.45E2
1225 2.45E2
1250 4.07E2
1275 6.62E2
1300 1.06E3
1320 1.52E3