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Author(s):
Jeffers, P.M.; Shaub, W.
Title:
Shock tube cis-trans isomerization studies
Journal:
J. Am. Chem. Soc.
Volume:
91
Page(s):
7706 - 7709
Year:
1969
Reference type:
Journal article
Squib:
1969JEF/SHA7706-7709
Reaction:
(Z)-2-C4H8 → (E)-2-C4H8
Reaction order:
1
Reference reaction:
tert-C4H9OH → Isobutene + H2O
Temperature:
1040 - 1320
K
Pressure: 0.13 - 0.27 bar
Rate expression:
2.4x1013 [s-1] e-257749 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
T (K) | k(T) [s-1] |
1040 |
2.72E0 |
1050 |
3.62E0 |
1075 |
7.18E0 |
1100 |
1.38E1 |
1125 |
2.59E1 |
1150 |
4.71E1 |
1175 |
8.36E1 |
1200 |
1.45E2 |
1225 |
2.45E2 |
1250 |
4.07E2 |
1275 |
6.62E2 |
1300 |
1.06E3 |
1320 |
1.52E3 |
|