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Accessibility information
Author(s):   Sprung, J.L.; Akimoto, H.; Pitts, J.N., Jr.
Title:   Nitrogen dioxide catalyzed cis-trans isomerization of cis-2-butene
Journal:   J. Am. Chem. Soc.
Volume:   93
Year:   1971
Reference type:   Journal article
Squib:   1971SPR/AKI4358

Reaction:   (Z)-2-C4H8(E)-2-C4H8
Reaction order:   2
Temperature:   298 - 338 K
Pressure:  1.33E-3 - 4.40E-2 bar
Rate expression:   2.09x10-13 [cm3/molecule s] e-50635 [±1014 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   (Z)-2-C4H8
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.79E-22
300 3.19E-22
325 1.52E-21
338 3.13E-21