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Author(s):   Teranishi, H.; Benson, S.W.
Title:   The kinetics of dehydrogenation of isobutane by iodine and the heat of formation of the t-butyl radical
Journal:   J. Am. Chem. Soc.
Volume:   85
Page(s):  
Year:   1963
Reference type:   Journal article
Squib:   1963TER/BEN2887

Reaction:   tert-C4H9 + HIiso-C4H10 + I
Reaction order:   2
Reference reaction:   tert-C4H9 + I2tert-C4H9I + I
Reference reaction order:   2
Temperature:   525 - 583 K
Pressure:  0.18 - 0.39 bar
Rate expression:   1.0 e-6693 [J/mole]/RT
Bath gas:   iso-C4H10
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
525 2.16E-1
550 2.31E-1
575 2.47E-1
583 2.51E-1