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Author(s):   Richards, P.D.; Ryther, R.J.; Weitz, E.
Title:   Diode laser probes of tert-butyl radical reaction kinetics: Reaction of C(CH3)3. with HBr, DBr, and HI
Journal:   J. Phys. Chem.
Volume:   94
Page(s):   3663 - 3667
Year:   1990
Reference type:   Journal article
Squib:   1990RIC/RYT3663-3667

Reaction:   tert-C4H9 + HIiso-C4H10 + I
Reaction order:   2
Temperature:   303 - 348 K
Pressure:  4.00E-3 - 1.33E-2 bar
Rate expression:   1.98x10-12 [±3.16x10-13 cm3/molecule s] e6394 [±8314472 J/mole]/RT
Bath gas:   SF6
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
303 2.50E-11
325 2.11E-11
348 1.80E-11