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Author(s):   Seetula, J.A.
Title:   Kinetics, thermochemistry and reactivity of reactions of some polyatomic free radicals with HI, HBr, Cl2 and Br2
Page(s):   1 - 45
Year:   1991
Book Title:   Annales Academiae Scientiarum Fennicae, Series A, II. Chemica, volume 234
Publisher address:   pub. Academia Scientiarum Fennica, Yliopistopaino, Helsinki, Finland
Reference type:   Book Chapter
Squib:   1991SEE1-45C

Reaction:   tert-C4H9 + HIiso-C4H10 + I
Reaction order:   2
Temperature:   294 - 552 K
Pressure:  1.00E-3 - 8.00E-3 bar
Rate expression:   3.16x10-12 [±5.98x10-13 cm3/molecule s] e6294 [±818 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
294 4.14E-11
300 3.93E-11
325 3.24E-11
350 2.74E-11
375 2.38E-11
400 2.09E-11
425 1.87E-11
450 1.70E-11
475 1.55E-11
500 1.43E-11
525 1.33E-11
550 1.25E-11
552 1.24E-11