 |
Home ©NIST, 2022 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Kinetic isotope effects for hydrogen abstraction from various saturated hydrocarbons by deuterium atoms in the gas phase
Journal: Ber. Bunsenges. Phys. Chem.
Volume: 90
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986FUJ/GAU375
Reaction:
Cyclopentane + D → Cyclopentyl + HD
Reaction order:
2
Reference reaction:
Cyclopentane-d10 + D → D2 + Cyclopentyl-d9
Reference reaction order:
2
Temperature:
363 - 463
K
Pressure: 1.80 bar
Rate expression:
6.3x10-1±6.3x10-2 e8240 [±329 J/mole]/RT
Bath gas:
Ne
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Ultrasonics
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 363 | 9.66E0 |
| 375 | 8.85E0 |
| 400 | 7.50E0 |
| 425 | 6.49E0 |
| 450 | 5.70E0 |
| 463 | 5.36E0 |