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Author(s):   Fujisaki, N.; Gaumann, T.; Ruf, A.
Title:   Kinetic isotope effects for hydrogen abstraction from various saturated hydrocarbons by deuterium atoms in the gas phase
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   90
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986FUJ/GAU375

Reaction:   Cyclopentane + DCyclopentyl + HD
Reaction order:   2
Reference reaction:   Cyclopentane-d10 + DD2 + Cyclopentyl-d9
Reference reaction order:   2
Temperature:   363 - 463 K
Pressure:  1.80 bar
Rate expression:   6.3x10-1±6.3x10-2 e8240 [±329 J/mole]/RT
Bath gas:   Ne
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Ultrasonics
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
363 9.66E0
375 8.85E0
400 7.50E0
425 6.49E0
450 5.70E0
463 5.36E0