Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Grotheer, H-H.; Louw, R.
Title:   The reaction of phenoxy radicals with mono-chlorobenzene and its meaning for gas-phase dioxin formation in incineration
Journal:   Symp. Int. Combust. Proc.
Volume:   26
Page(s):   2405 - 2411
Year:   1996
Reference type:   Journal article
Squib:   1996GRO/LOU2405-2411

Reaction:   Chlorobenzene + C6H5ODiphenyl ether + ·Cl
Reaction order:   2
Temperature:   728 - 984 K
Pressure:  1.01 bar
Rate expression:   7.97x10-13 [cm3/molecule s] e-102268 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Time resolution:   In both real time and by end product analysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
728 3.66E-20
750 6.01E-20
775 1.02E-19
800 1.68E-19
825 2.67E-19
850 4.14E-19
875 6.26E-19
900 9.25E-19
925 1.34E-18
950 1.90E-18
975 2.65E-18
984 2.97E-18