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Author(s):   Persky, A.
Title:   Intramolecular kinetic isotope effect in the reaction of fluorine atoms with methane-d2 (CH2D2)
Journal:   J. Chem. Phys.
Volume:   60
Page(s):   49 - 52
Year:   1974
Reference type:   Journal article
Squib:   1974PER49-52

Reaction:   CH2D2 + ·FHF + ·CHD2
Reaction order:   2
Reference reaction:   CH2D2 + ·F → CH2D + DF
Reference reaction order:   2
Temperature:   159 - 298 K
Rate expression:   8.09x10-1 e1147 [J/mole]/RT
Bath gas:   SF6
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
159 1.93E0
175 1.78E0
200 1.61E0
225 1.49E0
250 1.41E0
275 1.34E0
298 1.29E0