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Title: Intramolecular kinetic isotope effect in the reaction of fluorine atoms with methane-d2 (CH2D2)
Journal: J. Chem. Phys.
Volume: 60
Page(s): 49 - 52
Year: 1974
Reference type: Journal article
Squib: 1974PER49-52
Reaction:
CH2D2 + ·F → HF + ·CHD2
Reaction order:
2
Reference reaction:
CH2D2 + ·F → CH2D + DF
Reference reaction order:
2
Temperature:
159 - 298
K
Rate expression:
8.09x10-1 e1147 [J/mole]/RT
Bath gas:
SF6
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Electron beam
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 159 | 1.93E0 |
| 175 | 1.78E0 |
| 200 | 1.61E0 |
| 225 | 1.49E0 |
| 250 | 1.41E0 |
| 275 | 1.34E0 |
| 298 | 1.29E0 |