 |
Home ©NIST, 2022 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Reactions of trichloromethyl radicals with organosilicon compounds
Journal: Int. J. Chem. Kinet.
Volume: 16
Page(s): 1505 - 1518
Year: 1984
Reference type: Journal article
Squib: 1984RIC/TRE1505-1518
Reaction:
(CH3)2SiCl2 + ·CCl3 → CHCl3 + CH3Cl2SiCH2·
Reaction order:
2
Reference reaction:
·CCl3 + ·CCl3 → CCl3CCl3
Temperature:
463 - 588
K
Rate expression:
1.32x10-12 [cm3/molecule s] e-59033 [±2361 J/mole]/RT
Uncertainty:
1.58000004
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 463 | 2.89E-19 |
| 475 | 4.25E-19 |
| 500 | 8.98E-19 |
| 525 | 1.77E-18 |
| 550 | 3.26E-18 |
| 575 | 5.72E-18 |
| 588 | 7.52E-18 |