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Accessibility information
Author(s):   Pritchard, H.O.; Pyke, J.B.; Trotman-Dickenson, A.F.
Title:   The study of chlorine atom reactions in the gas phase
Journal:   J. Am. Chem. Soc.
Volume:   77
Year:   1955
Reference type:   Journal article
Squib:   1955PRI/PYK2629

Reaction:   C3H8 + ·Cl → Other Products + HCl
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Reference reaction order:   2
Temperature:   298 - 484 K
Pressure:  9.20E-2 - 0.25 bar
Rate expression:   1.47 e1380 [±8314472 J/mole]/RT
Bath gas:   C2H6
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 2.57E0
300 2.56E0
325 2.45E0
350 2.36E0
375 2.29E0
400 2.23E0
425 2.17E0
450 2.13E0
475 2.08E0
484 2.07E0