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Accessibility information
Author(s):   Lewis, R.S.; Sander, S.P.; Wagner, S.; Watson, R.T.
Title:   Temperature-dependent rate constants for the reaction of ground-state chlorine with simple alkanes
Journal:   J. Phys. Chem.
Volume:   84
Page(s):   2009 - 2015
Year:   1980
Reference type:   Journal article
Squib:   1980LEW/SAN2009-2015

Reaction:   C3H8 + ·Cl → Other Products + HCl
Reaction order:   2
Temperature:   220 - 607 K
Pressure:  1.33E-3 - 2.67E-3 bar
Rate expression:   1.36x10-10 [±1.36x10-11 cm3/molecule s] e366 [±209 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
220 1.66E-10
225 1.65E-10
250 1.62E-10
275 1.59E-10
300 1.57E-10
325 1.56E-10
350 1.54E-10
375 1.53E-10
400 1.52E-10
425 1.51E-10
450 1.50E-10
475 1.49E-10
500 1.48E-10
525 1.48E-10
550 1.47E-10
575 1.47E-10
600 1.46E-10
607 1.46E-10