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Author(s):   Takahashi, K.; Yamamot, O.; Inomata, T.
Title:   Direct measurements of the rate coefficients for the reactions of some hydrocarbons with chlorine atoms at high temperatures
Journal:   Proc. Combust. Inst.
Volume:   29
Page(s):   2447 - 2453
Year:   2002
Reference type:   Journal article
Squib:   2002TAK/YAM2447-2453

Reaction:   C3H8 + ·Cl → Other Products + HCl
Reaction order:   2
Temperature:   1100 - 1400 K
Rate expression:   1.7x10-10 [cm3/molecule s]
Uncertainty:   1.14999998
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Shock tube
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Shock tube study. Cl atoms produced by laser photolysis of SiCl4. Cl atoms detected using atomic resonance absorption. Also did ab initio calculations QCISD(T)/6-311G(d,p).

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