Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Bale, C.SE.; Canosa-Mas, C.E.; Shallcross, D.E.; Wayne, R.P.
Title:   A discharge-flow study of the kinetics of the reactions of IO with CH3O2 and CF3O2
Journal:   Phys. Chem. Chem. Phys.
Volume:   7
Page(s):   2164 - 2172
Year:   2005
Reference type:   Journal article
Squib:   2005BAL/CAN2164-2172

Reaction:   IO + CF3O2 → Products
Reaction order:   2
Temperature:   295 K
Pressure:  3.33E-3 bar
Rate expression:   3.7x10-11 [±9.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   IO generted by reaction of O-atoms with CF3I.
CF3O2 generated by reaction of F-atoms with CF3H in the presence of O2
Peroxyl radicals measured indirectly through titration by NO.

View full bibliographic record.