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Author(s):   Bale, C.SE.; Canosa-Mas, C.E.; Shallcross, D.E.; Wayne, R.P.
Title:   A discharge-flow study of the kinetics of the reactions of IO with CH3O2 and CF3O2
Journal:   Phys. Chem. Chem. Phys.
Volume:   7
Page(s):   2164 - 2172
Year:   2005
Reference type:   Journal article
Squib:   2005BAL/CAN2164-2172

Reaction:   IO + CF3O2 → Products
Reaction order:   2
Temperature:   295 K
Pressure:  3.33E-3 bar
Rate expression:   3.7x10-11 [±9.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   IO generted by reaction of O-atoms with CF3I.
CF3O2 generated by reaction of F-atoms with CF3H in the presence of O2
Peroxyl radicals measured indirectly through titration by NO.

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