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Title: A discharge-flow study of the kinetics of the reactions of IO with CH3O2 and CF3O2
Journal: Phys. Chem. Chem. Phys.
Volume: 7
Page(s): 2164 - 2172
Year: 2005
Reference type: Journal article
Squib: 2005BAL/CAN2164-2172
Reaction:
IO + CF3O2 → Products
Reaction order:
2
Temperature:
295
K
Pressure: 3.33E-3 bar
Rate expression:
3.7x10-11 [±9.0x10-12 cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Discharge
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
Comments:
IO generted by reaction of O-atoms with CF3I.
CF3O2 generated by reaction of F-atoms with CF3H in the presence of O2
Peroxyl radicals measured indirectly through titration by NO.
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