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Author(s):   Nikolaeva, E.V.; Egorov, D.L.; Chachkov, D.V.; Shamov, A.G.; Khrapkovskii, G.M.
Title:   Transition state structure of the reaction of homolytic dissociation of the C-N bond and competition between dif erent mechanisms of the primary act of gas-phase monomolecular decomposition of nitrobenzene
Journal:   Russ. Chem. Bull.
Volume:   68
Page(s):   1510 - 1519
Year:   2019
Reference type:   Journal article
Squib:   2019NIK/EGO1510-1519

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2019NIK/EGO1510-1519   NitrobenzenePhenyl + NO2  673 - 1273   1.26E18       2.97E05      1
  2019NIK/EGO1510-1519   NitrobenzeneC6H5O + NO  298 - 718   1.58E14       2.70E05   8.77E-34  1
  2019NIK/EGO1510-1519   Nitrobenzene → Nitrous acid phenyl ester  298 - 718   1.58E14       2.69E05   9.51E-34  1
  2019NIK/EGO1510-1519   Nitrobenzene → Nitrous acid phenyl ester  298 - 718   3.98E22       2.96E05   5.88E-30  1
  2019NIK/EGO1510-1519   Nitrobenzene → HONO (unspecified cis/trans isomer) + Benzyne  298 - 718   2.51E17       3.52E05   4.27E-45  1
  2019NIK/EGO1510-1519   Nitrobenzene → 6(S)-7-oxa-8-azabicyclo[4.2.0]octa-1(8),2,4-triene 8-oxide  298 - 718   3.98E11       2.68E05   4.76E-36  1

Search returned 6 records.