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Author(s):   Nikolaeva, E.V.; Egorov, D.L.; Chachkov, D.V.; Shamov, A.G.; Khrapkovskii, G.M.
Title:   Transition state structure of the reaction of homolytic dissociation of the C-N bond and competition between dif erent mechanisms of the primary act of gas-phase monomolecular decomposition of nitrobenzene
Journal:   Russ. Chem. Bull.
Volume:   68
Page(s):   1510 - 1519
Year:   2019
Reference type:   Journal article
Squib:   2019NIK/EGO1510-1519

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2019NIK/EGO1510-1519   NitrobenzenePhenyl + NO2  673 - 1273   1.26E18       2.97E05      1
  2019NIK/EGO1510-1519   NitrobenzeneC6H5O + NO  298 - 718   1.58E14       2.70E05   8.77E-34  1
  2019NIK/EGO1510-1519   Nitrobenzene → Nitrous acid phenyl ester  298 - 718   1.58E14       2.69E05   9.51E-34  1
  2019NIK/EGO1510-1519   Nitrobenzene → Nitrous acid phenyl ester  298 - 718   3.98E22       2.96E05   5.88E-30  1
  2019NIK/EGO1510-1519   Nitrobenzene → HONO (unspecified cis/trans isomer) + Benzyne  298 - 718   2.51E17       3.52E05   4.27E-45  1
  2019NIK/EGO1510-1519   Nitrobenzene → 6(S)-7-oxa-8-azabicyclo[4.2.0]octa-1(8),2,4-triene 8-oxide  298 - 718   3.98E11       2.68E05   4.76E-36  1

Search returned 6 records.