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Author(s):   Treves, K.;Shragina, L.; Rudich, Y.
Title:   Rate Coefficients for the Reactions of Cl Atoms with a Series of C3 -- C6 Hydroxyalkyl Nitrates at 290±2 K
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   5902 - 5907
Year:   2002
Reference type:   Journal article
Squib:   2002TRE/SHR5902-5907

Reaction:   1,4-butyl dinitrate + ·Cl → Products
Reaction order:   2
Reference reaction:   1-butyl nitrate + ·Cl → Products
Reference reaction order:   2
Temperature:   296 K
Pressure:  1.01 bar
Rate expression:   3.9x10-11±8.0x10-12
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography
Comments:   Relative rate measurement (reference reactions Cl + 1-butyl nitrate and Cl + 1-pentyl nitrate checked for internal consistency), collapsible teflon reactor, repeated short time photolysis of Cl2, solid-phase microextraction (SPME) sampling followed by GC/ECD, uncertainties are statistical plus 10% for reference reaction

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