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Author(s):   Farrell, J.T.; Taatjes, C.A.
Title:   Infrared frequency-modulation probing of Cl + C3H4 (allene, propyne) reactions: kinetics of HCl production from 292 to 850 K
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   4846 - 4856
Year:   1998
Reference type:   Journal article
Squib:   1998FAR/TAA4846-4856

Reaction:   CH2=C=CH2 + ·ClCH2=C=CH + HCl
Reaction order:   2
Temperature:   292 - 850 K
Pressure:  5.33E-3 - 1.33E-2 bar
Rate expression:   3.7x10-10 [±1.7x10-10 cm3/molecule s] e-13885 [±2378 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
292 1.21E-12
300 1.41E-12
350 3.13E-12
400 5.69E-12
450 9.05E-12
500 1.31E-11
550 1.78E-11
600 2.29E-11
650 2.83E-11
700 3.40E-11
750 3.99E-11
800 4.59E-11
850 5.19E-11