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Author(s):   Yee Quee, M.J.; Thynne, J.C.J.
Title:   The pressure dependence of the decomposition of the isopropoxyl radical
Journal:   J. Phys. Chem.
Volume:   72
Year:   1968
Reference type:   Journal article
Squib:   1968YEE/THY2824

Reaction:   (CH3)2CHO· + (iso-C3H7O)2 → Other Products + iso-C3H7OH
Reaction order:   2
Reference reaction:   C2H5CH(·)OH → CH3CHO + ·CH3
Reference reaction order:   1
Temperature:   395 - 428 K
Rate expression:   4.98x10-26 [cm3/molecule] e-50219 [±8314472 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   (iso-C3H7O)2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule]
395 1.14E-32
400 1.38E-32
425 3.35E-32
428 3.70E-32