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Title: Pyrolysis of ethanol: A shock-tube/TOF-MS and modeling study
Journal: Proc. Combust. Inst.
Volume: 35
Page(s): 465 - 472
Year: 2015
Book Title: ''
Editor: ''
Publisher: ''
Publisher address: ''
Comments: ''
Reference type: Journal article
Squib: 2015KIE/BAN465-472
Reaction:
C2H5OH → C2H4 + H2O
Reaction order:
1
Temperature:
1300 - 1510
K
Pressure: 1.10 bar
Rate expression:
2.5x1010 [±1.0x1010 s-1] e-193893 [J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Shock tube
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Mass spectrometry
Comments:
The estimated uncertainty of 40% is caused primarily by the data scatter in the kinetic product profiles.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1300 | 4.05E2 |
| 1325 | 5.68E2 |
| 1350 | 7.87E2 |
| 1375 | 1.08E3 |
| 1400 | 1.46E3 |
| 1425 | 1.95E3 |
| 1450 | 2.59E3 |
| 1475 | 3.40E3 |
| 1500 | 4.43E3 |
| 1510 | 4.91E3 |