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Accessibility information
Author(s):   Muller-Markgraf, W.; Troe, J.
Title:   Thermal decomposition of ethylbenzene, styrene, and bromophenylethane: UV absorption study in shock waves
Journal:   J. Phys. Chem.
Volume:   92
Year:   1988
Reference type:   Journal article
Squib:   1988MUL/TRO4914

Reaction:   StyreneBenzene + C2H2
Reaction order:   1
Temperature:   1640 - 2200 K
Pressure:  0.74 bar
Rate expression:   1.58x1011 [s-1] e-244445 [±12222 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1640 2.59E3
1650 2.89E3
1700 4.87E3
1750 7.99E3
1800 1.27E4
1850 1.98E4
1900 3.01E4
1950 4.48E4
2000 6.52E4
2050 9.34E4
2100 1.31E5
2150 1.82E5
2200 2.48E5