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Accessibility information
Author(s):   Grela, M.A.; Amorebieta, V.T.; Colussi, A.J.
Title:   Pyrolysis of styrene. Kinetics and mechanism of the equilibrium styrene = benzene + acetylene
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   9861 - 9865
Year:   1992
Reference type:   Journal article
Squib:   1992GRE/AMO9861-9865

Reaction:   StyreneBenzene + C2H2
Reaction order:   1
Temperature:   878 - 973 K
Pressure:  4.67E-2 - 9.07E-2 bar
Rate expression:   2.4x1014 [s-1] e-142177 [J/mole]/RT
Bath gas:   Benzene
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
878 8.35E5
900 1.34E6
925 2.25E6
950 3.66E6
973 5.59E6