 |
Home ©NIST, 2023 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Reactions of Oxygenated Radicals in the Gas Phase. Part 9. - Self-reactions of Isopropylperoxy Radicals
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 78
Page(s):
Year: 1982
Reference type: Journal article
Squib: 1982COW/WAD2535
Reaction:
(CH3)2CHO2 + (CH3)2CHO2 → Other Products + iso-C3H7OH
Reaction order:
2
Reference reaction:
(CH3)2CHO2 + (CH3)2CHO2 → Other Products + (CH3)2C(·)OH
Temperature:
302 - 373
K
Pressure: 0.67 bar
Rate expression:
4.05x10-14 [±5.31x10-15 cm3/molecule s] e-11973 [±956 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 302 | 3.44E-16 |
| 325 | 4.82E-16 |
| 350 | 6.62E-16 |
| 373 | 8.53E-16 |