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Accessibility information
Author(s):   Larsen, C.A.; Buchan, N.I.; Li, S.H.; Stringfellow, G.B.
Title:   Decomposition mechanisms of tertiarybutylarsine
Journal:   J. Cryst. Growth
Volume:   94
Page(s):   663 - 672
Year:   1989
Reference type:   Journal article
Squib:   1989LAR/BUC663-672

Reaction:   tert-C4H9AsH2iso-C4H10 + AsH
Reaction order:   1
Temperature:   625 - 870 K
Pressure:  1.01 bar
Rate expression:   1.2x1013 [s-1] e-173772 [J/mole]/RT
Bath gas:   D2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
625 3.60E-2
650 1.30E-1
675 4.29E-1
700 1.30E0
725 3.63E0
750 9.48E0
775 2.33E1
800 5.41E1
825 1.19E2
850 2.52E2
870 4.43E2