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Home ©NIST, 2013 Accessibility information |
Title: Decomposition mechanisms of tertiarybutylarsine
Journal: J. Cryst. Growth
Volume: 94
Page(s): 663 - 672
Year: 1989
Reference type: Journal article
Squib: 1989LAR/BUC663-672
Reaction:
tert-C4H9AsH2 → iso-C4H10 + AsH
Reaction order:
1
Temperature:
625 - 870
K
Pressure: 1.01 bar
Rate expression:
1.2x1013 [s-1] e-173772 [J/mole]/RT
Bath gas:
D2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 625 | 3.60E-2 |
| 650 | 1.30E-1 |
| 675 | 4.29E-1 |
| 700 | 1.30E0 |
| 725 | 3.63E0 |
| 750 | 9.48E0 |
| 775 | 2.33E1 |
| 800 | 5.41E1 |
| 825 | 1.19E2 |
| 850 | 2.52E2 |
| 870 | 4.43E2 |