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Title: System to measure relative rate constants of semivolatile organic compounds with hydroxyl radicals
Journal: Environ. Sci. Technol.
Volume: 30
Page(s): 301 - 306
Year: 1996
Reference type: Journal article
Squib: 1996AND/HIT301-306
Reaction:
Toluene + ·OH → Products
Reaction order:
2
Reference reaction:
Cyclohexane + ·OH → Cyclohexyl + H2O
Temperature:
296 - 363
K
Pressure: 1.01 bar
Rate expression:
1.73x10-12 [cm3/molecule s] e2943 [J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 296 | 5.71E-12 |
| 300 | 5.62E-12 |
| 325 | 5.13E-12 |
| 350 | 4.75E-12 |
| 363 | 4.58E-12 |