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Author(s):
Vasudevan, V.; Davidson, D.F.; Hanson, R.K.
Title:
High-temperature measurements of the reactions of OH with toluene and acetone
Journal:
J. Phys. Chem. A
Volume:
109
Page(s):
3352 - 3359
Year:
2005
Reference type:
Journal article
Squib:
2005VAS/DAV3352-3359
Reaction:
Toluene + ·OH → Products
Reaction order:
2
Temperature:
911 - 1389
K
Pressure: 2.10 - 2.86 bar
Rate expression:
no rate data available
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Pressure dependence:
None reported
Experimental procedure:
Shock tube
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
Comments:
No Arrhenius expression is given for the experimental k(T) dependence. Instead, rate constants for individual temperatures are presented in a tabular format.
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