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Home ©NIST, 2020 Accessibility information |
Title: Rate Constants for the Reaction of OH Radicals with Hydrocarbons in a Smog Chamber at Low Atmospheric Temperatures
Journal: Atmosphere
Volume: 9
Page(s):
Year: 2018
Reference type: Journal article
Squib: 2018HAN/SIE320
Reaction:
Toluene + ·OH → Products
Reaction order:
2
Temperature:
288
K
Pressure: 1.01 bar
Rate expression:
5.69x10-12 [±6.0x10-14 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
Rate constant value was also obtained at 248 K. This value is presented in Table 2S of the Supporting Information for the article. Toluene and n-pentane were used as reference compounds. The error bars are 2σ.
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