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Author(s):   Schliephake, V.; Mix, K.-H.; Wagner, H.Gg.
Title:   Investigations of the kinetics of the reactions of tetrahydrofurane, tetrahydropyrane, cyclopentanone and cyclohexanone with atomic oxygen
Journal:   Z. Phys. Chem. (Munich)
Volume:   150
Year:   1986
Reference type:   Journal article
Squib:   1986SCH/MIX1

Reaction:   Cyclopentanone + → Other Products + ·OH
Reaction order:   2
Temperature:   300 - 492 K
Pressure:  8.51E-3 - 1.60E-2 bar
Rate expression:   3.99x10-11 [±1.51x10-11 cm3/molecule s] e-18874 [±5662 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 2.06E-14
325 3.69E-14
350 6.08E-14
375 9.37E-14
400 1.37E-13
425 1.91E-13
450 2.57E-13
475 3.35E-13
492 3.95E-13