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Author(s):   Kozlov, S.N.; Orkin V.L.; Huie, R.E.; Kurylo, M.J.
Title:   OH Reactivity and UV Spectra of Propane, n-Propyl Bromide, and Isopropyl Bromide
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   1333 - 1338
Year:   2003
Reference type:   Journal article
Squib:   2003KOZ/ORK1333-1338

Reaction:   C3H8 + ·OH → Products
Reaction order:   2
Temperature:   210 - 300 K
Rate expression:   8.66x10-12 [cm3/molecule s] e-5113 [J/mole]/RT
Category:  Review
Data type:   Experimental value and limited review
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Resonance fluorescence
Comments:   All the available data from absolute rate constant measurements are within 5% of the recommended expression.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
210 4.63E-13
225 5.63E-13
250 7.40E-13
275 9.25E-13
300 1.11E-12