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Author(s):   Alecu, I.M.; Gao, Y.D.; Hsieh, P.C.; Sand, J.P.; Ors, A.; McLeod, A.; Marshall, P.
Title:   Studies of the kinetics and thermochemistry of the forward and reverse reaction Cl+C6H6=HCl+C6H5
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   3970 - 3976
Year:   2007
Reference type:   Journal article
Squib:   2007ALE/GAO3970-3976

Reaction:   Phenyl + HClBenzene + ·Cl
Reaction order:   2
Temperature:   294 - 748 K
Rate expression:   1.14x10-12 [cm3/molecule s] e5200 [J/mole]/RT
Category:  Review
Data type:   Experimental value and limited review
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
294 9.57E-12
300 9.17E-12
325 7.81E-12
350 6.81E-12
375 6.04E-12
400 5.44E-12
425 4.97E-12
450 4.58E-12
475 4.25E-12
500 3.98E-12
525 3.75E-12
550 3.55E-12
575 3.38E-12
600 3.23E-12
625 3.10E-12
650 2.98E-12
675 2.88E-12
700 2.79E-12
725 2.70E-12
748 2.63E-12