 |
Home ©NIST, 2023 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Hydrogen atom attack on perchloroethylene
Journal: Symp. Int. Combust. Proc.
Volume: 23
Page(s): 139 - 145
Year: 1991
Reference type: Journal article
Squib: 1991TSA/WAL139-145
Reaction:
C2Cl4 + H· → C2HCl3 + ·Cl
Reaction order:
2
Reference reaction:
1,3,5-Trimethylbenzene + H· → 1,3-Dimethylbenzene + ·CH3
Temperature:
950 - 1100
K
Pressure: 2.53 bar
Rate expression:
3.16x10-10 [cm3/molecule s] e-38163 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 950 | 2.52E-12 |
| 975 | 2.85E-12 |
| 1000 | 3.20E-12 |
| 1025 | 3.58E-12 |
| 1050 | 3.99E-12 |
| 1075 | 4.41E-12 |
| 1100 | 4.86E-12 |