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Author(s):   Tsang, W.; Walker, J.A.
Title:   Hydrogen atom attack on perchloroethylene
Journal:   Symp. Int. Combust. Proc.
Volume:   23
Page(s):   139 - 145
Year:   1991
Reference type:   Journal article
Squib:   1991TSA/WAL139-145

Reaction:   C2Cl4 + C2HCl3 + ·Cl
Reaction order:   2
Reference reaction:   1,3,5-Trimethylbenzene + 1,3-Dimethylbenzene + ·CH3
Temperature:   950 - 1100 K
Pressure:  2.53 bar
Rate expression:   3.16x10-10 [cm3/molecule s] e-38163 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
950 2.52E-12
975 2.85E-12
1000 3.20E-12
1025 3.58E-12
1050 3.99E-12
1075 4.41E-12
1100 4.86E-12