Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Pritchard, G.O.; Pritchard, H.O.; Schiff, H.I.; Trotman-Dickenson, A.F.
Title:   The reactions of trifluoromethyl radicals
Journal:   Trans. Faraday Soc.
Volume:   52
Year:   1956
Reference type:   Journal article
Squib:   1956PRI/PRI848

Reaction:   Toluene + ·CF3CHF3 + Benzyl
Reaction order:   2
Reference reaction:   ·CF3 + D2 → CDF3 + D
Reference reaction order:   2
Temperature:   526 - 588 K
Pressure:  1.33E-3 - 0.37 bar
Rate expression:   1.3 e-15465 [±4174 J/mole]/RT
Bath gas:   (CF3N)2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
526 3.79E-2
550 4.42E-2
575 5.12E-2
588 5.50E-2