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Accessibility information
Author(s):   Holmes, J.L.; Kutschke, K.O.
Title:   Reactions of trifluoromethyl radicals with benzene and toluene
Journal:   Trans. Faraday Soc.
Volume:   58
Year:   1962
Reference type:   Journal article
Squib:   1962HOL/KUT333

Reaction:   Toluene + ·CF3CHF3 + Benzyl
Reaction order:   2
Reference reaction:   Toluene + ·CF3 → Adduct
Temperature:   300 - 383 K
Rate expression:   6.46x10-13 [cm3/molecule s] e-24694 [±1239 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   (CF3)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 3.24E-17
325 6.94E-17
350 1.33E-16
375 2.35E-16
383 2.77E-16