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Title: Reactions of trifluoromethyl radicals with benzene and toluene
Journal: Trans. Faraday Soc.
Volume: 58
Page(s):
Year: 1962
Reference type: Journal article
Squib: 1962HOL/KUT333
Reaction:
Toluene + ·CF3 → CHF3 + Benzyl
Reaction order:
2
Reference reaction:
Toluene + ·CF3 → Adduct
Reference reaction order:
2
Temperature:
300 - 383
K
Rate expression:
1.83 e-9811 [±589 J/mole]/RT
Uncertainty:
1.22000003
Bath gas:
(CF3)2CO
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 300 | 3.58E-2 |
| 325 | 4.85E-2 |
| 350 | 6.28E-2 |
| 375 | 7.87E-2 |
| 383 | 8.40E-2 |