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Title: The reactions of bromine atoms and the strengths of C-H bonds
Journal: J. Am. Chem. Soc.
Volume: 81
Page(s):
Year: 1959
Reference type: Journal article
Squib: 1959FET/TRO5260
Reaction:
1-C4H10 + Br· → sec-C4H9 + HBr
Reaction order:
2
Reference reaction:
iso-C4H10 + Br· → tert-C4H9 + HBr
Reference reaction order:
2
Temperature:
261 - 371
K
Rate expression:
8.26 e-11391 [±114 J/mole]/RT
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 261 | 4.34E-2 |
| 275 | 5.67E-2 |
| 300 | 8.58E-2 |
| 325 | 1.22E-1 |
| 350 | 1.65E-1 |
| 371 | 2.06E-1 |