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Accessibility information
Author(s):   Takahashi, K.; Kunz, A.; Woiki, D.; Roth, P.
Title:   Thermal decomposition of tin tetrachloride based on Cl- and Sn-concentration measurements
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   5246 - 5253
Year:   2000
Reference type:   Journal article
Squib:   2000TAK/KUN5246-5253

Reaction:   SnCl(2Π) → Sn(3P) + ·Cl
Reaction order:   2
Temperature:   1250 - 1700 K
Pressure:  1.70E13 - 8.90E13 bar
Rate expression:   3.0x10-10 [cm3/molecule s] e-265000 [±40000 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Shock tube
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1250 2.53E-21
1275 4.18E-21
1300 6.75E-21
1325 1.07E-20
1350 1.67E-20
1375 2.57E-20
1400 3.89E-20
1425 5.80E-20
1450 8.53E-20
1475 1.24E-19
1500 1.77E-19
1525 2.51E-19
1550 3.52E-19
1575 4.88E-19
1600 6.70E-19
1625 9.10E-19
1650 1.22E-18
1675 1.63E-18
1700 2.16E-18