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Author(s):   Schutze, N.; Zhong, X.Y.; Kirschbaum, S.; Bejan, I.; Barnes, I.; Benter, T.
Title:   Relative kinetic measurements of rate coefficients for the gas-phase reactions of Cl atoms and OH radicals with a series of methyl alkyl esters
Journal:   Atmos. Environ.
Volume:   44
Page(s):   5407 - 5414
Year:   2010
Reference type:   Journal article
Squib:   2010SCH/ZHO5407-5414

Reaction:   ·Cl + Butanoic acid, 2-methyl-, methyl ester → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   9.41x10-11 [±1.39x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Ethane, toluene, and ethene were used as reference compounds. The value of the rate constant was obtained by averaging the values obtained with individual reference compounds and taking errors which encompass the extremes of all determinations.

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