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Author(s):   Schutze, N.; Zhong, X.Y.; Kirschbaum, S.; Bejan, I.; Barnes, I.; Benter, T.
Title:   Relative kinetic measurements of rate coefficients for the gas-phase reactions of Cl atoms and OH radicals with a series of methyl alkyl esters
Journal:   Atmos. Environ.
Volume:   44
Page(s):   5407 - 5414
Year:   2010
Reference type:   Journal article
Squib:   2010SCH/ZHO5407-5414

Reaction:   ·Cl + Butanoic acid, 2-methyl-, methyl ester → Products
Reaction order:   2
Reference reaction:   C2H4 + ·Cl → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   9.08x10-1
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Uncertainty of the rate constant ration is not reported.

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