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Author(s):   Donohoue, D.L.; Bauer, D.; Hynes, A.J.
Title:   Temperature and pressure dependent rate coefficients for the reaction of Hg with Cl and the reaction of Cl with Cl: A pulsed laser photolysis-pulsed laser induced fluorescence study
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   7732 - 7741
Year:   2005
Reference type:   Journal article
Squib:   2005DON/BAU7732-7741

Reaction:   He + ·Cl + ·ClHe + Cl2
Reaction order:   3
Temperature:   296 K
Pressure:  0.27 - 0.80 bar
Rate expression:   5.17x10-33 [±4.9x10-34 cm6/molecule2 s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Third-order rate constants calculated by forcing fits through the origin.

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