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Accessibility information
Author(s):   Kerr, J.A.; Smith, B.J.A.; Trotman-Dickenson, A.F.; Young, J.C.
Title:   The abstraction of halogen atoms from alkyl halides by the trichlorosilyl radical
Journal:   J. Chem. Soc. A
Page(s):   510 - 513
Year:   1968
Reference type:   Journal article
Squib:   1968KER/SMI510-513

Reaction:   iso-C3H7Cl + SiCl32-C3H7 + SiCl4
Reaction order:   2
Reference reaction:   iso-C4H9Cl + SiCl3iso-C4H9 + SiCl4
Reference reaction order:   2
Temperature:   370 - 566 K
Rate expression:   1.45±4.3x10-2 e2336 [±117 J/mole]/RT
Bath gas:   SiHCl3
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
370 3.10E0
375 3.07E0
400 2.93E0
425 2.81E0
450 2.71E0
475 2.62E0
500 2.54E0
525 2.48E0
550 2.42E0
566 2.38E0