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Title: The abstraction of halogen atoms from alkyl halides by the trichlorosilyl radical
Journal: J. Chem. Soc. A
Page(s): 510 - 513
Year: 1968
Reference type: Journal article
Squib: 1968KER/SMI510-513
Reaction:
iso-C3H7Cl + SiCl3 → 2-C3H7 + SiCl4
Reaction order:
2
Reference reaction:
iso-C4H9Cl + SiCl3 → iso-C4H9 + SiCl4
Reference reaction order:
2
Temperature:
370 - 566
K
Rate expression:
1.45±4.3x10-2 e2336 [±117 J/mole]/RT
Bath gas:
SiHCl3
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 370 | 3.10E0 |
| 375 | 3.07E0 |
| 400 | 2.93E0 |
| 425 | 2.81E0 |
| 450 | 2.71E0 |
| 475 | 2.62E0 |
| 500 | 2.54E0 |
| 525 | 2.48E0 |
| 550 | 2.42E0 |
| 566 | 2.38E0 |