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Title: Elementary steps in the pyrolysis of toluene and benzyl radicals
Journal: Z. Phys. Chem. (Neue Folge)
Volume: 167
Page(s): 1 - 16
Year: 1990
Reference type: Journal article
Squib: 1990HIP/REI1-16
Reaction:
Benzyl → Products
Reaction order:
1
Temperature:
1700 - 1900
K
Rate expression:
2.0x1015 [s-1] e-350039 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1700 | 3.51E4 |
| 1725 | 5.03E4 |
| 1750 | 7.13E4 |
| 1775 | 1.00E5 |
| 1800 | 1.39E5 |
| 1825 | 1.92E5 |
| 1850 | 2.62E5 |
| 1875 | 3.55E5 |
| 1900 | 4.76E5 |