Author(s):   Cadman, P.; Tilsley, G.M.; Trotman-Dickenson, A.F.
Title:   Reactions of trichlorosilyl radicals with n-propyl chloride, cyclopentyl chloride, and carbon tetrachloride
Journal:   J. Chem. Soc. A
Page(s):   1370 - 1372
Year:   1969
Reference type:   Journal article
Squib:   1969CAD/TIL1370-1372

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	k(298.00 K)	Order
1969CAD/TIL1370-1372	CCl₄ + SiCl₃ → ·CCl₃ + SiCl₄	353 - 553	42.60	-1.41E04		2
Reference reaction: CH₃Br + SiCl₃ → ·CH₃ + Silane, bromotrichloro-					2
1969CAD/TIL1370-1372	CCl₄ + SiCl₃ → ·CCl₃ + SiCl₄	353 - 553	11.50	-8398		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1969CAD/TIL1370-1372	1-C₄H₉Cl + SiCl₃ → 1-C₄H₉ + SiCl₄	353 - 443	2.50	-5396		2
Reference reaction: Cyclopentane, chloro- + SiCl₃ → Cyclopentyl + SiCl₄					2
1969CAD/TIL1370-1372	n-C₃H₇Cl + SiCl₃ → 1-C₃H₇ + SiCl₄	353 - 483	1.26	-4598		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1969CAD/TIL1370-1372	n-C₃H₇Cl + SiCl₃ → 1-C₃H₇ + SiCl₄	353 - 483	0.96	665		2
Reference reaction: 1-C₄H₉Cl + SiCl₃ → 1-C₄H₉ + SiCl₄					2
1969CAD/TIL1370-1372	Cyclopentane, chloro- + SiCl₃ → Cyclopentyl + SiCl₄	353 - 443	0.52	-1.06E04		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2

Search returned 6 records.