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Author(s):   Yasunaga, K.; Kubo, S.; Hoshikawa, H.; Kamesawa, T.; Hidaka, Y.
Title:   Shock-tube and modeling study of acetaldehyde pyrolysis and oxidation
Journal:   Int. J. Chem. Kinet.
Volume:   40
Page(s):   73 - 102
Year:   2008
Reference type:   Journal article
Squib:   2008YAS/KUB73-102

Reaction:   CH3CHOCH4 + CO
Reaction order:   1
Temperature:   1000 - 1700 K
Pressure:  1.22 - 2.84 bar
Rate expression:   1.0x1015 [s-1] e-355640 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Experimental procedure:   Shock tube
Time resolution:   In real time
Analytical technique:   Other (Vis-UV)
Comments:   The reacted mixture was analyzed by gaschromatographic, IR-laser absorption, UV absorption and IR-emission equipments.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 2.65E-4
1050 2.03E-3
1100 1.30E-2
1150 7.03E-2
1200 3.31E-1
1250 1.38E0
1300 5.13E0
1350 1.74E1
1400 5.38E1
1450 1.54E2
1500 4.13E2
1550 1.04E3
1600 2.45E3
1650 5.52E3
1700 1.18E4