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Author(s):   Walker, R.F.; Phillips, L.
Title:   The kinetics of disproportionation-combination reactions between the s-butoxy-radical and nitric oxide, and of the pyrolysis of the O-O bond in di-s-butyl peroxide in the gas phase
Journal:   J. Chem. Soc. London A
Page(s):   2103 - 2106
Year:   1968
Reference type:   Journal article
Squib:   1968WAL/PHI2103-2106

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1968WAL/PHI2103-2106   Peroxide, bis(1-methylpropyl) → CH3CH2CH(CH3)O· + CH3CH2CH(CH3)O·  373 - 413   1.80E15       1.52E05      1
  1968WAL/PHI2103-2106   NO + CH3CH2CH(CH3)O· → C2H5COCH3 + HNO  373 - 413   2.16E-14              2
  1968WAL/PHI2103-2106   NO + CH3CH2CH(CH3)O· → C2H5COCH3 + HNO  373 - 413   0.26              2
  Reference reaction:  NO + CH3CH2CH(CH3)O· → CH3CH2CH(CH3)ONO 2
  1968WAL/PHI2103-2106   CH3CH2CH(CH3)O· + CH3CH2CH(CH3)O· → Peroxide, bis(1-methylpropyl)  373 - 413   1.41E-12              2

Search returned 4 records.