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Author(s):   Sway, M.I.; Waddington, D.J.
Title:   Reactions of oxygenated radicals in the gas phase. Part 12. The reactions of isopropylperoxy radical and alkenes
Journal:   J. Chem. Soc. Perkin Trans. 2
Year:   1983
Reference type:   Journal article
Squib:   1983SWA/WAD139

Reaction:   (CH3)2C=CHCH3 + (CH3)2CHO2(CH3)2CHO· + 2,2,3-trimethyl-oxirane
Reaction order:   2
Temperature:   303 - 408 K
Pressure:  0.67 bar
Rate expression:   1.78x10-13 [cm3/molecule s] e-48224 [±1929 J/mole]/RT
Uncertainty:   2.240000009536743
Bath gas:   O2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
303 8.64E-22
325 3.16E-21
350 1.13E-20
375 3.41E-20
400 8.96E-20
408 1.19E-19