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Author(s):   Tarr, A.M.; Strausz, O.P.; Gunning, H.E.
Title:   Reactions of the ethynyl radical. Part 1 - Hydrogen abstraction from alkanes
Journal:   Trans. Faraday Soc.
Volume:   61
Page(s):   1946 - 1959
Year:   1965
Reference type:   Journal article
Squib:   1965TAR/STR1946-1959

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1965TAR/STR1946-1959   CH4 + ·C2H → C2H2 + ·CH3  298   0.02           0.02  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
  1965TAR/STR1946-1959   C2H6 + ·C2H → C2H2 + ·C2H5  298   0.40           0.40  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
  1965TAR/STR1946-1959   C2H5Cl + ·C2H → Other Products + C2H2  298   0.14           0.14  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
  1965TAR/STR1946-1959   Cyclopropane + ·C2H → C2H2 + Cyclopropyl  298   0.21           0.21  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
  1965TAR/STR1946-1959   iso-C4H10 + ·C2H → Other Products + C2H2  298   1.24           1.24  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
  1965TAR/STR1946-1959   1-C4H10 + ·C2H → Other Products + C2H2  298   1.05           1.05  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
  1965TAR/STR1946-1959   Cyclohexane + ·C2H → C2H2 + Cyclohexyl  298   3.20           3.20  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
  1965TAR/STR1946-1959   Spiropentane + ·C2H → C2H2 + Spiropentyl  298   0.64           0.64  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
  1965TAR/STR1946-1959   Cyclobutane + ·C2H → C2H2 + Cyclobutyl  298   1.35           1.35  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
  1965TAR/STR1946-1959   Cyclopentane + ·C2H → C2H2 + Cyclopentyl  298   2.10           2.10  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
  1965TAR/STR1946-1959   neo-C5H12 + ·C2H → C2H2 + Neopentyl  298   1.10           1.10  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
  1965TAR/STR1946-1959   2,2,3,3-Tetramethylbutane + ·C2H → C2H2 + (CH3)3CC(CH3)2CH2  298   1.20           1.20  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
  1965TAR/STR1946-1959   Cyclohexane-d12 + ·C2H → HC≡CD + Cyclohexyl-d11  298   2.30           2.30  2
  Reference reaction:  HC≡CBr + ·C2H → 1,3-Butadiyne + Br· 2
Search returned 13 records.