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Accessibility information
Author(s):   Brown, T.C.; King, K.D.
Title:   Very low-pressure pyrolysis (VLPP) of methyl- and ethynyl- cyclopentanes and cyclohexanes
Journal:   Int. J. Chem. Kinet.
Volume:   21
Page(s):   251 - 266
Year:   1989
Reference type:   Journal article
Squib:   1989BRO/KIN251-266

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1989BRO/KIN251-266   Methylcyclopentane → Other Products + 1-C6H12  1020 - 1220   2.51E16       3.41E05      1
  1989BRO/KIN251-266   Methylcyclopentane → Other Products + C2H5CH2C(CH3)=CH2  1020 - 1220   3.98E16       3.53E05      1
  1989BRO/KIN251-266   Methylcyclopentane·CH3 + Cyclopentyl  1020 - 1220   1.26E12       3.68E05      1
  1989BRO/KIN251-266   Methylcyclohexane → Other Products + n-C4H9C(CH3)=CH2  1010 - 1210   5.01E16       3.60E05      1
  1989BRO/KIN251-266   Methylcyclohexane1-C7H14 + 2-C7H14  1010 - 1210   2.51E16       3.45E05      1
  1989BRO/KIN251-266   Methylcyclohexane·CH3 + Cyclohexyl  1010 - 1210   1.26E16       3.68E05      1
  1989BRO/KIN251-266   Cyclopentane, ethynyl- → Isomers + CH2=CH(CH2)3C≡CH  925 - 1210   1.00E16       3.04E05      1
  1989BRO/KIN251-266   Cyclohexylacetylene → Isomers + CH2=CH(CH2)4C≡CH  861 - 1210   1.26E16       3.03E05      1
  1989BRO/KIN251-266   CyclohexylacetyleneCyclohexane, ethenylidene-  861 - 1210   2.51E13       2.47E05      1
  1989BRO/KIN251-266   Cyclopentane, ethenylidene- → Cyclopentane, ethynyl-  925 - 1210   1.00E13       2.54E05      1

Search returned 10 records.