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Author(s):   Javadi, M.S.; Sondergaard, R.; Nielsen, O.J.; Hurley, M.D.; Wallington, T.J.
Title:   Atmospheric chemistry of trans-CF3CH = CHF: products and mechanisms of hydroxyl radical and chlorine atom initiated oxidation
Journal:   Atmos. Chem. Phys.
Volume:   8
Page(s):   3141 - 3147
Year:   2008
Reference type:   Journal article
Squib:   2008JAV/SON3141-3147

Reaction:   O2 + CF3CClHO(.) → CF3COCl + HO2
Reaction order:   2
Reference reaction:   CF3CClHO(.) → Products
Reference reaction order:   1
Temperature:   295 K
Pressure:  0.93 bar
Rate expression:   4.6x10-19 [±1.9x10-19 cm3/molecule]
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)

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