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Title: Atmospheric chemistry of trans-CF3CH = CHF: products and mechanisms of hydroxyl radical and chlorine atom initiated oxidation
Journal: Atmos. Chem. Phys.
Volume: 8
Page(s): 3141 - 3147
Year: 2008
Reference type: Journal article
Squib: 2008JAV/SON3141-3147
Reaction:
O2 + CF3CClHO(.) → CF3COCl + HO2
Reaction order:
2
Reference reaction:
CF3CClHO(.) → Products
Reference reaction order:
1
Temperature:
295
K
Pressure: 0.93 bar
Rate expression:
4.6x10-19 [±1.9x10-19 cm3/molecule]
Category: Experiment
Data type:
Relative rate value measured
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
In real time
Analytical technique:
Fourier transform (FTIR)
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